Difference between revisions of "Principle Behind Mother-Daughter Relationship"
Jonpo@uio.no (talk | contribs) |
(→Basic Theory) |
||
(One intermediate revision by one other user not shown) | |||
Line 1: | Line 1: | ||
− | ==== Basic Theory ==== | + | ==== Basic Theory ==== |
A radionuclide generator, also popularly called a “cow”, is composed of a mother-daughter radionuclide relationship where the mother has a longer half-life than the daughter. The daughter is continuously produced by decay of the mother in the generator system, and the daughter can be separated (“milked”) from the generator (“cow) by chemical or physical methods. In this Exercise we are going to use one such system defined in more detail below. | A radionuclide generator, also popularly called a “cow”, is composed of a mother-daughter radionuclide relationship where the mother has a longer half-life than the daughter. The daughter is continuously produced by decay of the mother in the generator system, and the daughter can be separated (“milked”) from the generator (“cow) by chemical or physical methods. In this Exercise we are going to use one such system defined in more detail below. | ||
Line 13: | Line 13: | ||
[[Image:Mother-Daughter conclusion.jpg|center|350px]] | [[Image:Mother-Daughter conclusion.jpg|center|350px]] | ||
− | At this situation we say that we have obtained radioactive equilibrium in the generator system. A practical equilibrium is defined to be reached when t ≤ T<sub>½</sub> where D<sub>2</sub> ≤ 0.999•D<sub>1</sub>. | + | At this situation we say that we have obtained radioactive equilibrium in the generator system. A practical equilibrium is defined to be reached when t ≤ T<sub>½</sub> where D<sub>2</sub> ≤ 0.999•D<sub>1</sub>. |
− | ==== Practical Approach ==== | + | ==== Practical Approach ==== |
In general, it is not practical to wait until radioactive equilibrium has been reached before utilizing the generated daughter activity in laboratory experiments. By using that λ<sub>2</sub> = ln 2 / T<sub>½,2</sub> and setting t = T<sub>½,2</sub> into (2.2), we obtain:[[Image:Mother-Daughter conclusion2.jpg|center|200px]] | In general, it is not practical to wait until radioactive equilibrium has been reached before utilizing the generated daughter activity in laboratory experiments. By using that λ<sub>2</sub> = ln 2 / T<sub>½,2</sub> and setting t = T<sub>½,2</sub> into (2.2), we obtain:[[Image:Mother-Daughter conclusion2.jpg|center|200px]] | ||
Line 21: | Line 21: | ||
i.e. we have obtained 50% of the maximum obtainable activity already after a growing-in time of one daughter half-life. | i.e. we have obtained 50% of the maximum obtainable activity already after a growing-in time of one daughter half-life. | ||
− | Fig.2.1 illustrates how the activity of the daughter increases as a function of the growing-in time in units of T<sub>½,2</sub>:<br>[[Image:Mother-Daugher figure 2-1.jpg|center|350px]]In the lab exercise where we made a calibration source from uranium, we used the grand daughter of <sup>238</sup>U (as U<sub>3</sub>O<sub>8</sub>) to get a high-energy beta emitter. The first part of the <sup>238</sup>U natural radioactive series may be written as[[Image: | + | Fig.2.1 illustrates how the activity of the daughter increases as a function of the growing-in time in units of T<sub>½,2</sub>:<br>[[Image:Mother-Daugher figure 2-1.jpg|center|350px]]In the lab exercise where we made a calibration source from uranium, we used the grand daughter of <sup>238</sup>U (as U<sub>3</sub>O<sub>8</sub>) to get a high-energy beta emitter. The first part of the <sup>238</sup>U natural radioactive series may be written as[[Image:U238 decay chain.jpg|center|500px]] |
− | We observe that this part of the series gives possibility for two generator systems, i.e. | + | We observe that this part of the series gives possibility for two generator systems, i.e. <sup>238</sup>U ⇒ <sup>234</sup>Th and <sup>234</sup>Th ⇒ <sup>234m</sup>Pa. The first is not practical in short laboratory exercises because of the relatively long half-life of the daughter (24 d), but the second system is suitable.<br><br> |
− | |||
− |
Latest revision as of 14:37, 28 February 2014
Basic Theory
A radionuclide generator, also popularly called a “cow”, is composed of a mother-daughter radionuclide relationship where the mother has a longer half-life than the daughter. The daughter is continuously produced by decay of the mother in the generator system, and the daughter can be separated (“milked”) from the generator (“cow) by chemical or physical methods. In this Exercise we are going to use one such system defined in more detail below.
From basic lectures on decay we have the following relation between a radioactive nuclide and its radioactive daughter:where the index 1 denotes the mother and index 2 the daughter.If λ1 << λ2, i.e. the half-life of the daughter is much shorter than the half-life of the mother, we have:
If the growing-in time t on the generator in (2.2) is much longer than the half-life of the daughter (T½,2), the exponent will go towards the limit of 0. This again results in the fact that the disintegration rate of the daughter equals the disintegration rate of the mother on the generator, i.e. the maximum activity that can be produced of the daughter on the generator equals the activity of the mother. Expressed in mathematical terms for (2.2):
At this situation we say that we have obtained radioactive equilibrium in the generator system. A practical equilibrium is defined to be reached when t ≤ T½ where D2 ≤ 0.999•D1.
Practical Approach
In general, it is not practical to wait until radioactive equilibrium has been reached before utilizing the generated daughter activity in laboratory experiments. By using that λ2 = ln 2 / T½,2 and setting t = T½,2 into (2.2), we obtain:i.e. we have obtained 50% of the maximum obtainable activity already after a growing-in time of one daughter half-life.
Fig.2.1 illustrates how the activity of the daughter increases as a function of the growing-in time in units of T½,2:In the lab exercise where we made a calibration source from uranium, we used the grand daughter of 238U (as U3O8) to get a high-energy beta emitter. The first part of the 238U natural radioactive series may be written as
We observe that this part of the series gives possibility for two generator systems, i.e. 238U ⇒ 234Th and 234Th ⇒ 234mPa. The first is not practical in short laboratory exercises because of the relatively long half-life of the daughter (24 d), but the second system is suitable.